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Application of ortho‐palladated homoveratrylamine complex containing mixed phosphorus–nitrogen donors in the Suzuki reaction
Title
Authors
Abdol R Hajipour, Hannaneh Rahimi, Fatemeh Rafiee
Publication date
2012/9/1
Journal name
Applied Organometallic Chemistry
Volume
26
Issue
9
Pages
467
Description
The catalytic activity of [Pd {C6H2 (CH2CH2NH2)-(OMe) 2, 3, 4} Br (PPh3)] monomeric ortho-
palladated complex of homoveratrylamine and triphenylphosphine was investigated in the
Suzuki cross-coupling reaction of various aryl halides with aryl boronic acids. The
substituted biaryls were produced in excellent yields using a catalytic amount of this
complex in ethanol at 60 C. Copyright© 2012 John Wiley & Sons, Ltd. Keywords: Suzuki
reaction; catalyst; ortho-palladated complex; triphenylphosphine
palladated complex of homoveratrylamine and triphenylphosphine was investigated in the
Suzuki cross-coupling reaction of various aryl halides with aryl boronic acids. The
substituted biaryls were produced in excellent yields using a catalytic amount of this
complex in ethanol at 60 C. Copyright© 2012 John Wiley & Sons, Ltd. Keywords: Suzuki
reaction; catalyst; ortho-palladated complex; triphenylphosphine
Journal Papers
Month/Season:
Spring
Year:
2013