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- فارسی
Synthesis of substituted biaryls via Suzuki, Stille and Hiyama cross-coupling and homo-coupling reactions by CN-dimeric and monomeric ortho-palladated catalysts
Authors
Abdol R Hajipour, Fatemeh Rafiee
Publication date
2013/7/1
Journal name
Applied Organometallic Chemistry
Volume
27
Issue
7
Pages
412-418
Publisher
Wiley-Blackwell
Description
The catalytic activity of dimeric [Pd {C6H2 (CH2CH2NH2)–(OMe) 2, 2, 3}(m-Br)] 2 and
monomeric [Pd {C6H2 (CH2CH2NH2)–(OMe) 2, 2, 3} Br (PPh3)] complexes as efficient,
stable and air-and moisture-tolerant catalysts was investigated in the Suzuki, Stille and
Hiyama cross-coupling and homo-coupling reactions of various aryl halides. Substituted
biaryls were produced in excellent yields in short reaction times using catalytic amounts of
these complexes. The monomeric complex was demonstrated to be more active than the ...
monomeric [Pd {C6H2 (CH2CH2NH2)–(OMe) 2, 2, 3} Br (PPh3)] complexes as efficient,
stable and air-and moisture-tolerant catalysts was investigated in the Suzuki, Stille and
Hiyama cross-coupling and homo-coupling reactions of various aryl halides. Substituted
biaryls were produced in excellent yields in short reaction times using catalytic amounts of
these complexes. The monomeric complex was demonstrated to be more active than the ...
Publications
Month/Season:
July
Year:
2013