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Synthesis of tertiary aryl amines of various aryl halides and secondary amines using ortho-palladated complex of tribenzylamine
Authors
Abdol R Hajipour, Fatemeh Dordahan, Fatemeh Rafiee
Publication date
2013/12/1
Journal name
Applied Organometallic Chemistry
Volume
27
Issue
12
Pages
704-706
Publisher
Wiley-Blackwell
Description
The activity of dimeric [Pd {C6H4 (CH2N (CH2Ph) 2)}(μ-Br)] 2 complex as an efficient, air-
and moisture-tolerant catalyst was investigated in amination reactions of various aryl halides
with secondary amines. Substituted tertiary aryl amines were produced in excellent yields
and short reaction times using catalytic amounts of this dimeric complex in DMSO at 120 C.
Copyright© 2013 John Wiley & Sons, Ltd. Keywords: palladium catalyst; ortho-palladated
complex; C―N cross-coupling reaction
and moisture-tolerant catalyst was investigated in amination reactions of various aryl halides
with secondary amines. Substituted tertiary aryl amines were produced in excellent yields
and short reaction times using catalytic amounts of this dimeric complex in DMSO at 120 C.
Copyright© 2013 John Wiley & Sons, Ltd. Keywords: palladium catalyst; ortho-palladated
complex; C―N cross-coupling reaction
Publications
Month/Season:
December
Year:
2013