Synthesis of a new palladium salt using N‐benzyl DABCO chloride and its application in Suzuki reaction

Abdol Reza Hajipour, Ifa Mahboobi Dehbane, Fatemeh Rafiee

2012/12/1

Applied Organometallic Chemistry

26

12

743

A palladium catalyst was synthesized using N-benzyl DABCO chloride and palladium 
chloride. The structure of this catalyst was characterized and then the catalyst was used in 
Suzuki cross-coupling reaction of different aryl halides with arylboronic acids. All substrates 
afforded the corresponding products in good to high yields in the presence of low amounts 
of the catalyst. Under the heating conditions employed, cheaper and more available aryl 
chlorides gave relatively high yields in the Suzuki reaction. Copyright© 2012 John Wiley & ...